Analysis of the products of photochemistry using tunable diode lasers, with application to the multiphoton dissociation of chloroform

P. H. Beckwith; J. J. Orlando; J. Reid; D. R. Smith

doi:10.1016/0047-2670(86)87101-5

Analysis of the products of photochemistry using tunable diode lasers, with application to the multiphoton dissociation of chloroform

P. H. Beckwith, J. J. Orlando, J. Reid, D. R. Smith

Experimental Science Section

McMaster University

Research output: Contribution to journal › Article › peer-review

Abstract

Tunable diode lasers (TDLs) remain relatively unexploited as a tool in analytical chemistry. We show that TDLs are sensitive analytical tool for investigating the products of photochemical reactions in the gas phase, and give examples from experiments on the IR photochemistry of chloroform. The sensitivity of the TDL technique is such that we can measure the few parts per million of DCL formed by photolysis of natural abundance CDCl₃ in CHCl₃.

Original language	English
Pages (from-to)	267-279
Number of pages	13
Journal	Journal of Photochemistry
Volume	34
Issue number	3
DOIs	https://doi.org/10.1016/0047-2670(86)87101-5
State	Published - Sep 1986

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title = "Analysis of the products of photochemistry using tunable diode lasers, with application to the multiphoton dissociation of chloroform",

abstract = "Tunable diode lasers (TDLs) remain relatively unexploited as a tool in analytical chemistry. We show that TDLs are sensitive analytical tool for investigating the products of photochemical reactions in the gas phase, and give examples from experiments on the IR photochemistry of chloroform. The sensitivity of the TDL technique is such that we can measure the few parts per million of DCL formed by photolysis of natural abundance CDCl3 in CHCl3.",

author = "Beckwith, \{P. H.\} and Orlando, \{J. J.\} and J. Reid and Smith, \{D. R.\}",

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AU - Beckwith, P. H.

AU - Orlando, J. J.

AU - Reid, J.

AU - Smith, D. R.

PY - 1986/9

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N2 - Tunable diode lasers (TDLs) remain relatively unexploited as a tool in analytical chemistry. We show that TDLs are sensitive analytical tool for investigating the products of photochemical reactions in the gas phase, and give examples from experiments on the IR photochemistry of chloroform. The sensitivity of the TDL technique is such that we can measure the few parts per million of DCL formed by photolysis of natural abundance CDCl3 in CHCl3.

AB - Tunable diode lasers (TDLs) remain relatively unexploited as a tool in analytical chemistry. We show that TDLs are sensitive analytical tool for investigating the products of photochemical reactions in the gas phase, and give examples from experiments on the IR photochemistry of chloroform. The sensitivity of the TDL technique is such that we can measure the few parts per million of DCL formed by photolysis of natural abundance CDCl3 in CHCl3.

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DO - 10.1016/0047-2670(86)87101-5

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AN - SCOPUS:46149134744

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VL - 34

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IS - 3

ER -

Analysis of the products of photochemistry using tunable diode lasers, with application to the multiphoton dissociation of chloroform

Abstract

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