Atmospheric oxidation mechanism of methyl formate

T. J. Wallington; M. D. Hurley; T. Maurer; I. Barnes; K. H. Becker; G. S. Tyndall; J. J. Orlando; A. S. Pimentel; M. Bilde

doi:10.1021/jp0041398

Atmospheric oxidation mechanism of methyl formate

T. J. Wallington
, M. D. Hurley
, T. Maurer
, I. Barnes
, K. H. Becker
, G. S. Tyndall
, J. J. Orlando
, A. S. Pimentel
, M. Bilde

Experimental Science Section

Research output: Contribution to journal › Article › peer-review

44 Scopus citations

Abstract

The atmospheric oxidation mechanism of methyl formate was studied. The products following Cl atom initiated oxidation of methyl formate in 700-760 Torr of air in the presence and absence of NO_x at 296 ± 2 K were investigated using three different Fourier transform infrared (FTIR) smog chamber techniques. The infrared spectrum of the peroxynitrate was recorded, and absorption cross sections (base e) of (1.8 ± 0.1) × 10^-18 and (4.2 ± 0.2) × 10^-18 cm² molecule^-1 at 1836 and 1236 cm^-1, respectively, were determined.

Original language	English
Pages (from-to)	5146-5154
Number of pages	9
Journal	Journal of Physical Chemistry A
Volume	105
Issue number	21
DOIs	https://doi.org/10.1021/jp0041398
State	Published - May 31 2001

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title = "Atmospheric oxidation mechanism of methyl formate",

abstract = "The atmospheric oxidation mechanism of methyl formate was studied. The products following Cl atom initiated oxidation of methyl formate in 700-760 Torr of air in the presence and absence of NOx at 296 ± 2 K were investigated using three different Fourier transform infrared (FTIR) smog chamber techniques. The infrared spectrum of the peroxynitrate was recorded, and absorption cross sections (base e) of (1.8 ± 0.1) × 10-18 and (4.2 ± 0.2) × 10-18 cm2 molecule-1 at 1836 and 1236 cm-1, respectively, were determined.",

author = "Wallington, \{T. J.\} and Hurley, \{M. D.\} and T. Maurer and I. Barnes and Becker, \{K. H.\} and Tyndall, \{G. S.\} and Orlando, \{J. J.\} and Pimentel, \{A. S.\} and M. Bilde",

year = "2001",

month = may,

day = "31",

doi = "10.1021/jp0041398",

language = "English",

volume = "105",

pages = "5146--5154",

journal = "Journal of Physical Chemistry A",

issn = "1089-5639",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Atmospheric oxidation mechanism of methyl formate

AU - Wallington, T. J.

AU - Hurley, M. D.

AU - Maurer, T.

AU - Barnes, I.

AU - Becker, K. H.

AU - Tyndall, G. S.

AU - Orlando, J. J.

AU - Pimentel, A. S.

AU - Bilde, M.

PY - 2001/5/31

Y1 - 2001/5/31

N2 - The atmospheric oxidation mechanism of methyl formate was studied. The products following Cl atom initiated oxidation of methyl formate in 700-760 Torr of air in the presence and absence of NOx at 296 ± 2 K were investigated using three different Fourier transform infrared (FTIR) smog chamber techniques. The infrared spectrum of the peroxynitrate was recorded, and absorption cross sections (base e) of (1.8 ± 0.1) × 10-18 and (4.2 ± 0.2) × 10-18 cm2 molecule-1 at 1836 and 1236 cm-1, respectively, were determined.

AB - The atmospheric oxidation mechanism of methyl formate was studied. The products following Cl atom initiated oxidation of methyl formate in 700-760 Torr of air in the presence and absence of NOx at 296 ± 2 K were investigated using three different Fourier transform infrared (FTIR) smog chamber techniques. The infrared spectrum of the peroxynitrate was recorded, and absorption cross sections (base e) of (1.8 ± 0.1) × 10-18 and (4.2 ± 0.2) × 10-18 cm2 molecule-1 at 1836 and 1236 cm-1, respectively, were determined.

UR - https://www.scopus.com/pages/publications/0035978237

U2 - 10.1021/jp0041398

DO - 10.1021/jp0041398

M3 - Article

AN - SCOPUS:0035978237

SN - 1089-5639

VL - 105

SP - 5146

EP - 5154

JO - Journal of Physical Chemistry A

JF - Journal of Physical Chemistry A

IS - 21

ER -

Atmospheric oxidation mechanism of methyl formate

Abstract

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