Atmospheric oxidation mechanism of methyl formate

T. J. Wallington; M. D. Hurley; T. Maurer; I. Barnes; K. H. Becker; G. S. Tyndall; J. J. Orlando; A. S. Pimentel; M. Bilde

doi:10.1021/jp0041398

Atmospheric oxidation mechanism of methyl formate

T. J. Wallington, M. D. Hurley, T. Maurer, I. Barnes, K. H. Becker, G. S. Tyndall, J. J. Orlando, A. S. Pimentel, M. Bilde

Experimental Science Section

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44 Scopus citations

Abstract

The atmospheric oxidation mechanism of methyl formate was studied. The products following Cl atom initiated oxidation of methyl formate in 700-760 Torr of air in the presence and absence of NO_x at 296 ± 2 K were investigated using three different Fourier transform infrared (FTIR) smog chamber techniques. The infrared spectrum of the peroxynitrate was recorded, and absorption cross sections (base e) of (1.8 ± 0.1) × 10^-18 and (4.2 ± 0.2) × 10^-18 cm² molecule^-1 at 1836 and 1236 cm^-1, respectively, were determined.

Original language	English
Pages (from-to)	5146-5154
Number of pages	9
Journal	Journal of Physical Chemistry A
Volume	105
Issue number	21
DOIs	https://doi.org/10.1021/jp0041398
State	Published - May 31 2001

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title = "Atmospheric oxidation mechanism of methyl formate",

abstract = "The atmospheric oxidation mechanism of methyl formate was studied. The products following Cl atom initiated oxidation of methyl formate in 700-760 Torr of air in the presence and absence of NOx at 296 ± 2 K were investigated using three different Fourier transform infrared (FTIR) smog chamber techniques. The infrared spectrum of the peroxynitrate was recorded, and absorption cross sections (base e) of (1.8 ± 0.1) × 10-18 and (4.2 ± 0.2) × 10-18 cm2 molecule-1 at 1836 and 1236 cm-1, respectively, were determined.",

author = "Wallington, \{T. J.\} and Hurley, \{M. D.\} and T. Maurer and I. Barnes and Becker, \{K. H.\} and Tyndall, \{G. S.\} and Orlando, \{J. J.\} and Pimentel, \{A. S.\} and M. Bilde",

year = "2001",

month = may,

day = "31",

doi = "10.1021/jp0041398",

language = "English",

volume = "105",

pages = "5146--5154",

journal = "Journal of Physical Chemistry A",

issn = "1089-5639",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Atmospheric oxidation mechanism of methyl formate

AU - Wallington, T. J.

AU - Hurley, M. D.

AU - Maurer, T.

AU - Barnes, I.

AU - Becker, K. H.

AU - Tyndall, G. S.

AU - Orlando, J. J.

AU - Pimentel, A. S.

AU - Bilde, M.

PY - 2001/5/31

Y1 - 2001/5/31

N2 - The atmospheric oxidation mechanism of methyl formate was studied. The products following Cl atom initiated oxidation of methyl formate in 700-760 Torr of air in the presence and absence of NOx at 296 ± 2 K were investigated using three different Fourier transform infrared (FTIR) smog chamber techniques. The infrared spectrum of the peroxynitrate was recorded, and absorption cross sections (base e) of (1.8 ± 0.1) × 10-18 and (4.2 ± 0.2) × 10-18 cm2 molecule-1 at 1836 and 1236 cm-1, respectively, were determined.

AB - The atmospheric oxidation mechanism of methyl formate was studied. The products following Cl atom initiated oxidation of methyl formate in 700-760 Torr of air in the presence and absence of NOx at 296 ± 2 K were investigated using three different Fourier transform infrared (FTIR) smog chamber techniques. The infrared spectrum of the peroxynitrate was recorded, and absorption cross sections (base e) of (1.8 ± 0.1) × 10-18 and (4.2 ± 0.2) × 10-18 cm2 molecule-1 at 1836 and 1236 cm-1, respectively, were determined.

UR - https://www.scopus.com/pages/publications/0035978237

U2 - 10.1021/jp0041398

DO - 10.1021/jp0041398

M3 - Article

AN - SCOPUS:0035978237

SN - 1089-5639

VL - 105

SP - 5146

EP - 5154

JO - Journal of Physical Chemistry A

JF - Journal of Physical Chemistry A

IS - 21

ER -

Atmospheric oxidation mechanism of methyl formate

Abstract

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