Determination of index of refraction and size of supermicrometer particles from light scattering measurements at two angles

A twin angle optical-particle counter (TAOPC) that measures forward scattering at 40° and 74° was developed to determine the index of refraction of atmospheric particles. An error analysis indicates that measurement uncertainties for size at 40° are between 4 and 10% for particles >1.5 μm and between 5 and 15% at 74°. For the index of refraction determination, the measurement uncertainties lead to index of refraction uncertainties between 1 and 2.5%. The instrument was tested on nonabsorbing spherical particles of known composition and size in the laboratory. The majority of the estimated indices of refraction were within ±1% of the expected indices, and size determination was within acceptable error. The instrument was also tested on non-spherical absorbing particles to determine the complex index of refraction of ambient mineral dust particles collected in Laramie, Wyoming, in February 2006. The index of refraction was determined with the particle number ratio approach and was estimated to be in the range 1.60-1.67 for the real part and 0.009-0.0104 for the imaginary part. Simultaneously with the TAOPC measurements, particles were collected on polycarbonate filters for computer-controlled scanning electron microscopy (CCSEM) analysis. Index of refraction calculated from this analysis was in the range 1.61-1.66 for the real part and 0.008-0.012 for the imaginary part. Particles were also collected for longer periods on two different filter pack systems in February 2006. Estimates of index of refraction from these measurements compared well with the CCSEM analysis.