TY - JOUR
T1 - Integrated intensities of OH vibrational overtones in alcohols
AU - Phillips, J. A.
AU - Orlando, J. J.
AU - Tyndall, G. S.
AU - Vaida, V.
PY - 1998/11/6
Y1 - 1998/11/6
N2 - Intensities for several OH vibrational overtone bands have been measured for vapor-phase methanol, ethanol, and isopropanol. The trends in the intensities as a function of excitation level have been modeled by two empirical approaches, yielding intensity predictions for the higher overtone transitions, up to 7ν(OH). These methods were also applied to recent HNO3 overtone measurements, resulting in new intensity predictions for higher, photochemically active overtone bands, which are compared with ab initio estimates.
AB - Intensities for several OH vibrational overtone bands have been measured for vapor-phase methanol, ethanol, and isopropanol. The trends in the intensities as a function of excitation level have been modeled by two empirical approaches, yielding intensity predictions for the higher overtone transitions, up to 7ν(OH). These methods were also applied to recent HNO3 overtone measurements, resulting in new intensity predictions for higher, photochemically active overtone bands, which are compared with ab initio estimates.
UR - https://www.scopus.com/pages/publications/0001097632
U2 - 10.1016/S0009-2614(98)01045-8
DO - 10.1016/S0009-2614(98)01045-8
M3 - Article
AN - SCOPUS:0001097632
SN - 0009-2614
VL - 296
SP - 377
EP - 383
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 3-4
ER -