On the processes influencing the vertical distribution of ozone over the central Himalayas: Analysis of yearlong ozonesonde observations

First yearlong (2011) balloon-borne measurements of ozone vertical distribution (EN-SCI 2ZV7 ECC Ozonesonde) and meteorological parameters (iMet-1-RSB 403MHz GPS Radiosonde) over Nainital (79.5°E, 29.4°N, 1958mamsl) in the central Himalayas are presented. Lower tropospheric ozone shows a prominent seasonality with highest levels during spring (~70-110ppbv in May) and lowest levels during summer-monsoon (~20-50ppbv), which is consistent with the ground-based observations. The lower tropospheric ozone minimum coincides with highest values of relative humidity (80-100%) during the summer-monsoon. However, ozone mixing ratios in the middle-upper troposphere show less pronounced and different seasonality. Influences of subtropical jets are observed (wind speed: ~40-80ms^-1) in the middle-upper troposphere, particularly during winter. A stratospheric intrusion event during winter is observed, which enhances the ozone levels by ~180% in the middle-upper troposphere. A noticeable feature of secondary ozone peaks (~140-250ppbv) is observed in the middle troposphere (~8-12km), more frequently during spring. Ozone levels in 2-4km altitude range are higher by 19.9±4.6ppbv during the springtime high fire activity period over the northern India. Moreover, the lower tropospheric ozone levels over Nainital during spring are found to be considerably (~30ppbv) higher than those over Ahmedabad in the western India. This ozone enhancement is attributed mainly to the regional pollution of the Indo-Gangetic Plain (IGP) supplemented with the northern Indian biomass burning. It is suggested that regional photochemistry and biomass burning processes play controlling role in the lower troposphere, while, the middle-upper tropospheric variations are driven by dynamical processes including advection and stratospheric intrusion.