Radiative transfer modeling for the EOS Terra satellite Measurement of Pollution in the Troposphere (MOPITT) instrument

This paper describes the radiative transfer modeling effort in support of the EOS Measurements of Pollution in the Troposphere (MOPITT) instrument. MOPITT is due to be launched on the AM-1 Terra platform in the summer of 1999 and is a nadir-viewing gas correlation radiometer designed to measure CO and CH₄ in the troposphere using a CO thermal channel at 4.7 μm and reflected solar channels for CO at 2.3 μm and CH₄ at 2.2 μm. We describe the spectroscopic considerations and radiative transfer studies that have been performed for this instrument and the implications for operational algorithm design. We outline the construction of MOPITT project forward models, both the research codes and the fast transmittance module that forms part of the operational retrieval algorithm. Several different approaches have been considered for these models: full line-by-line calculations using the general purpose line-by-line transmittance and radiance model GENLN2, absorption coefficient look-up tables, and regression techniques using a recurrence parameterization of transmittance. These models are capable of reproducing MOPITT channel signals and their dependence on temperature, viewing geometry, and the mixing ratios of target and contaminating gases.