Rate coefficient upper limits for the BrONO2 and ClONO2 + O3 reactions

James B. Burkholder; John J. Orlando

doi:10.1029/98GL02626

Rate coefficient upper limits for the BrONO₂ and ClONO₂ + O₃ reactions

James B. Burkholder, John J. Orlando

Experimental Science Section

Research output: Contribution to journal › Article › peer-review

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Abstract

The gas phase reactions BrONO₂ and ClONO₂ + O₃ → Products (k₁ and k₃) were examined at 235 ± 2 K and 700 Torr N₂ using a Fourier transform infrared spectrometer coupled to a temperature regulated long path absorption cell. The loss of BrONO₂ and ClONO₂ were measured to be independent of the O₃ concentration yielding k₁ < 1 x10^-20 cm³ molecule^-1 s^-1 and k₃ < 4 x10^-21 cm³ molecule^-1 s^-1.

Original language	English
Pages (from-to)	3567-3569
Number of pages	3
Journal	Geophysical Research Letters
Volume	25
Issue number	19
DOIs	https://doi.org/10.1029/98GL02626
State	Published - Oct 1 1998

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10.1029/98GL02626

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title = "Rate coefficient upper limits for the BrONO2 and ClONO2 + O3 reactions",

abstract = "The gas phase reactions BrONO2 and ClONO2 + O3 → Products (k1 and k3) were examined at 235 ± 2 K and 700 Torr N2 using a Fourier transform infrared spectrometer coupled to a temperature regulated long path absorption cell. The loss of BrONO2 and ClONO2 were measured to be independent of the O3 concentration yielding k1 < 1 x10-20 cm3 molecule-1 s-1 and k3 < 4 x10-21 cm3 molecule-1 s-1.",

author = "Burkholder, \{James B.\} and Orlando, \{John J.\}",

year = "1998",

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doi = "10.1029/98GL02626",

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journal = "Geophysical Research Letters",

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T1 - Rate coefficient upper limits for the BrONO2 and ClONO2 + O3 reactions

AU - Burkholder, James B.

AU - Orlando, John J.

PY - 1998/10/1

Y1 - 1998/10/1

N2 - The gas phase reactions BrONO2 and ClONO2 + O3 → Products (k1 and k3) were examined at 235 ± 2 K and 700 Torr N2 using a Fourier transform infrared spectrometer coupled to a temperature regulated long path absorption cell. The loss of BrONO2 and ClONO2 were measured to be independent of the O3 concentration yielding k1 < 1 x10-20 cm3 molecule-1 s-1 and k3 < 4 x10-21 cm3 molecule-1 s-1.

AB - The gas phase reactions BrONO2 and ClONO2 + O3 → Products (k1 and k3) were examined at 235 ± 2 K and 700 Torr N2 using a Fourier transform infrared spectrometer coupled to a temperature regulated long path absorption cell. The loss of BrONO2 and ClONO2 were measured to be independent of the O3 concentration yielding k1 < 1 x10-20 cm3 molecule-1 s-1 and k3 < 4 x10-21 cm3 molecule-1 s-1.

UR - https://www.scopus.com/pages/publications/0032193177

U2 - 10.1029/98GL02626

DO - 10.1029/98GL02626

M3 - Article

AN - SCOPUS:0032193177

SN - 0094-8276

VL - 25

SP - 3567

EP - 3569

JO - Geophysical Research Letters

JF - Geophysical Research Letters

IS - 19

ER -

Rate coefficient upper limits for the BrONO₂ and ClONO₂ + O₃ reactions

Abstract

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