Rate coefficients and mechanisms of the reaction of Cl-atoms with a series of unsaturated hydrocarbons under atmospheric conditions

John J. Orlando; Geoffrey S. Tyndall; Eric C. Apel; Daniel D. Riemer; Suzanne E. Paulson

doi:10.1002/kin.10135

Rate coefficients and mechanisms of the reaction of Cl-atoms with a series of unsaturated hydrocarbons under atmospheric conditions

John J. Orlando, Geoffrey S. Tyndall, Eric C. Apel, Daniel D. Riemer, Suzanne E. Paulson

Experimental Science Section

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Abstract

The rate coefficients and mechanisms of the reaction of Cl-atoms with a series of unsaturated hydrocarbons under atmospheric conditions were studied. It was observed the product yielded from both trans-2-butene and 1-butene were found to be oxygen dependent. The results showed that the variation of the product yielded with O₂ in the case of 1-butene resulted from competitive reaction pathways for the two β-chlorobutoxy radicals involved in the oxidation.

Original language	English
Pages (from-to)	334-353
Number of pages	20
Journal	International Journal of Chemical Kinetics
Volume	35
Issue number	8
DOIs	https://doi.org/10.1002/kin.10135
State	Published - Aug 2003

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10.1002/kin.10135

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abstract = "The rate coefficients and mechanisms of the reaction of Cl-atoms with a series of unsaturated hydrocarbons under atmospheric conditions were studied. It was observed the product yielded from both trans-2-butene and 1-butene were found to be oxygen dependent. The results showed that the variation of the product yielded with O2 in the case of 1-butene resulted from competitive reaction pathways for the two β-chlorobutoxy radicals involved in the oxidation.",

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AU - Orlando, John J.

AU - Tyndall, Geoffrey S.

AU - Apel, Eric C.

AU - Riemer, Daniel D.

AU - Paulson, Suzanne E.

PY - 2003/8

Y1 - 2003/8

N2 - The rate coefficients and mechanisms of the reaction of Cl-atoms with a series of unsaturated hydrocarbons under atmospheric conditions were studied. It was observed the product yielded from both trans-2-butene and 1-butene were found to be oxygen dependent. The results showed that the variation of the product yielded with O2 in the case of 1-butene resulted from competitive reaction pathways for the two β-chlorobutoxy radicals involved in the oxidation.

AB - The rate coefficients and mechanisms of the reaction of Cl-atoms with a series of unsaturated hydrocarbons under atmospheric conditions were studied. It was observed the product yielded from both trans-2-butene and 1-butene were found to be oxygen dependent. The results showed that the variation of the product yielded with O2 in the case of 1-butene resulted from competitive reaction pathways for the two β-chlorobutoxy radicals involved in the oxidation.

UR - https://www.scopus.com/pages/publications/0042843585

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DO - 10.1002/kin.10135

M3 - Article

AN - SCOPUS:0042843585

SN - 0538-8066

VL - 35

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EP - 353

JO - International Journal of Chemical Kinetics

JF - International Journal of Chemical Kinetics

IS - 8

ER -

Rate coefficients and mechanisms of the reaction of Cl-atoms with a series of unsaturated hydrocarbons under atmospheric conditions

Abstract

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