Time-resolved tunable diode laser detection of products of CF2HCl IRMPD: A linestrength measurement for CF2

J. J. Orlando; J. Reid; D. R. Smith

doi:10.1016/0009-2614(87)85053-4

Time-resolved tunable diode laser detection of products of CF₂HCl IRMPD: A linestrength measurement for CF₂

J. J. Orlando
, J. Reid
, D. R. Smith

Experimental Science Section

McMaster University

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Tunable diode laser transient detection of CF₂ C₂F₄, and HCl following infrared multiphoton dissociation (IRMPD) of CF₂HCl has been achieved. Quantification of the HCl and C₂F₄ leads to the calculation of an infrared absorption linestrength and the ν₁ bandstrength for CF₂ (X̃¹A₁). In addition, the rate coefficient for recombination of CF₂ was found to be (1.4± 0.4) × 10¹⁰ cm³ mol^-1 s^-1.

Original language	English
Pages (from-to)	423-427
Number of pages	5
Journal	Chemical Physics Letters
Volume	141
Issue number	5
DOIs	https://doi.org/10.1016/0009-2614(87)85053-4
State	Published - Nov 20 1987

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title = "Time-resolved tunable diode laser detection of products of CF2HCl IRMPD: A linestrength measurement for CF2",

abstract = "Tunable diode laser transient detection of CF2 C2F4, and HCl following infrared multiphoton dissociation (IRMPD) of CF2HCl has been achieved. Quantification of the HCl and C2F4 leads to the calculation of an infrared absorption linestrength and the ν1 bandstrength for CF2 ({\~X}1A1). In addition, the rate coefficient for recombination of CF2 was found to be (1.4± 0.4) × 1010 cm3 mol-1 s-1.",

author = "Orlando, \{J. J.\} and J. Reid and Smith, \{D. R.\}",

year = "1987",

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doi = "10.1016/0009-2614(87)85053-4",

language = "English",

volume = "141",

pages = "423--427",

journal = "Chemical Physics Letters",

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T1 - Time-resolved tunable diode laser detection of products of CF2HCl IRMPD

T2 - A linestrength measurement for CF2

AU - Orlando, J. J.

AU - Reid, J.

AU - Smith, D. R.

PY - 1987/11/20

Y1 - 1987/11/20

N2 - Tunable diode laser transient detection of CF2 C2F4, and HCl following infrared multiphoton dissociation (IRMPD) of CF2HCl has been achieved. Quantification of the HCl and C2F4 leads to the calculation of an infrared absorption linestrength and the ν1 bandstrength for CF2 (X̃1A1). In addition, the rate coefficient for recombination of CF2 was found to be (1.4± 0.4) × 1010 cm3 mol-1 s-1.

AB - Tunable diode laser transient detection of CF2 C2F4, and HCl following infrared multiphoton dissociation (IRMPD) of CF2HCl has been achieved. Quantification of the HCl and C2F4 leads to the calculation of an infrared absorption linestrength and the ν1 bandstrength for CF2 (X̃1A1). In addition, the rate coefficient for recombination of CF2 was found to be (1.4± 0.4) × 1010 cm3 mol-1 s-1.

UR - https://www.scopus.com/pages/publications/24044492033

U2 - 10.1016/0009-2614(87)85053-4

DO - 10.1016/0009-2614(87)85053-4

M3 - Article

AN - SCOPUS:24044492033

SN - 0009-2614

VL - 141

SP - 423

EP - 427

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 5

ER -

Time-resolved tunable diode laser detection of products of CF₂HCl IRMPD: A linestrength measurement for CF₂

Abstract

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