Two new lanthanide members of francisite family Cu3Ln(SeO3)2O2Cl (Ln = Eu, Lu)

K. V. Zakharov; E. A. Zvereva; E. S. Kuznetsova; P. S. Berdonosov; V. A. Dolgikh; M. M. Markina; A. V. Olenev; A. A. Shakin; O. S. Volkova; A. N. Vasiliev

doi:10.1016/j.jallcom.2016.05.213

Two new lanthanide members of francisite family Cu₃Ln(SeO₃)₂O₂Cl (Ln = Eu, Lu)

K. V. Zakharov
, E. A. Zvereva
, E. S. Kuznetsova
, P. S. Berdonosov
, V. A. Dolgikh
, M. M. Markina
, A. V. Olenev
, A. A. Shakin
, O. S. Volkova
, A. N. Vasiliev

Lomonosov Moscow State University
Sine Theta Ltd.
National University of Science and Technology "MISiS"
Ural Federal University

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

Two new lanthanide compounds, Cu₃Ln(SeO₃)₂O₂Cl, Ln = Eu and Lu, with mineral francisite structure were synthesized under vacuum in sealed quartz tubes. The Rietveld refinement of the structure results in orthorhombic unit cell, space group Pmmn. The arrangement of magnetically active Cu²⁺ ions in francisite structure corresponds to buckled kagomé type lattice. Both compounds were characterized in measurements of ac-magnetic susceptibility, dc-magnetization, X-band electron spin resonance and specific heat in the range 2-320 K under magnetic field up to 9 T. The ferromagnetic interactions dominate in both compounds at elevated temperatures. The Eu (Lu) francisite manifests antiferromagnetic order at T_N = 36 (38) K and undergoes the field-induced metamagnetic transition into canted ferrimagnetic state at B_C = 2.6 (3.0) T. The magnetization loops of both compounds evidence hysteretic behavior above B_C.

Original language	English
Pages (from-to)	442-447
Number of pages	6
Journal	Journal of Alloys and Compounds
Volume	685
DOIs	https://doi.org/10.1016/j.jallcom.2016.05.213
State	Published - Nov 15 2016
Externally published	Yes

Keywords

Oxide materials
Phase transitions
Rare earth alloys and compounds
Thermodynamic properties
Transition metal alloys and compounds

Access to Document

10.1016/j.jallcom.2016.05.213

Cite this

@article{6af264fd1aa6434e85803c3af5ac4f71,

title = "Two new lanthanide members of francisite family Cu3Ln(SeO3)2O2Cl (Ln = Eu, Lu)",

abstract = "Two new lanthanide compounds, Cu3Ln(SeO3)2O2Cl, Ln = Eu and Lu, with mineral francisite structure were synthesized under vacuum in sealed quartz tubes. The Rietveld refinement of the structure results in orthorhombic unit cell, space group Pmmn. The arrangement of magnetically active Cu2+ ions in francisite structure corresponds to buckled kagom{\'e} type lattice. Both compounds were characterized in measurements of ac-magnetic susceptibility, dc-magnetization, X-band electron spin resonance and specific heat in the range 2-320 K under magnetic field up to 9 T. The ferromagnetic interactions dominate in both compounds at elevated temperatures. The Eu (Lu) francisite manifests antiferromagnetic order at TN = 36 (38) K and undergoes the field-induced metamagnetic transition into canted ferrimagnetic state at BC = 2.6 (3.0) T. The magnetization loops of both compounds evidence hysteretic behavior above BC.",

keywords = "Oxide materials, Phase transitions, Rare earth alloys and compounds, Thermodynamic properties, Transition metal alloys and compounds",

author = "Zakharov, \{K. V.\} and Zvereva, \{E. A.\} and Kuznetsova, \{E. S.\} and Berdonosov, \{P. S.\} and Dolgikh, \{V. A.\} and Markina, \{M. M.\} and Olenev, \{A. V.\} and Shakin, \{A. A.\} and Volkova, \{O. S.\} and Vasiliev, \{A. N.\}",

note = "Publisher Copyright: {\textcopyright} 2016 Elsevier B.V.",

year = "2016",

month = nov,

day = "15",

doi = "10.1016/j.jallcom.2016.05.213",

language = "English",

volume = "685",

pages = "442--447",

journal = "Journal of Alloys and Compounds",

issn = "0925-8388",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Two new lanthanide members of francisite family Cu3Ln(SeO3)2O2Cl (Ln = Eu, Lu)

AU - Zakharov, K. V.

AU - Zvereva, E. A.

AU - Kuznetsova, E. S.

AU - Berdonosov, P. S.

AU - Dolgikh, V. A.

AU - Markina, M. M.

AU - Olenev, A. V.

AU - Shakin, A. A.

AU - Volkova, O. S.

AU - Vasiliev, A. N.

PY - 2016/11/15

Y1 - 2016/11/15

N2 - Two new lanthanide compounds, Cu3Ln(SeO3)2O2Cl, Ln = Eu and Lu, with mineral francisite structure were synthesized under vacuum in sealed quartz tubes. The Rietveld refinement of the structure results in orthorhombic unit cell, space group Pmmn. The arrangement of magnetically active Cu2+ ions in francisite structure corresponds to buckled kagomé type lattice. Both compounds were characterized in measurements of ac-magnetic susceptibility, dc-magnetization, X-band electron spin resonance and specific heat in the range 2-320 K under magnetic field up to 9 T. The ferromagnetic interactions dominate in both compounds at elevated temperatures. The Eu (Lu) francisite manifests antiferromagnetic order at TN = 36 (38) K and undergoes the field-induced metamagnetic transition into canted ferrimagnetic state at BC = 2.6 (3.0) T. The magnetization loops of both compounds evidence hysteretic behavior above BC.

AB - Two new lanthanide compounds, Cu3Ln(SeO3)2O2Cl, Ln = Eu and Lu, with mineral francisite structure were synthesized under vacuum in sealed quartz tubes. The Rietveld refinement of the structure results in orthorhombic unit cell, space group Pmmn. The arrangement of magnetically active Cu2+ ions in francisite structure corresponds to buckled kagomé type lattice. Both compounds were characterized in measurements of ac-magnetic susceptibility, dc-magnetization, X-band electron spin resonance and specific heat in the range 2-320 K under magnetic field up to 9 T. The ferromagnetic interactions dominate in both compounds at elevated temperatures. The Eu (Lu) francisite manifests antiferromagnetic order at TN = 36 (38) K and undergoes the field-induced metamagnetic transition into canted ferrimagnetic state at BC = 2.6 (3.0) T. The magnetization loops of both compounds evidence hysteretic behavior above BC.

KW - Oxide materials

KW - Phase transitions

KW - Rare earth alloys and compounds

KW - Thermodynamic properties

KW - Transition metal alloys and compounds

UR - https://www.scopus.com/pages/publications/84975034793

U2 - 10.1016/j.jallcom.2016.05.213

DO - 10.1016/j.jallcom.2016.05.213

M3 - Article

AN - SCOPUS:84975034793

SN - 0925-8388

VL - 685

SP - 442

EP - 447

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

ER -

Two new lanthanide members of francisite family Cu₃Ln(SeO₃)₂O₂Cl (Ln = Eu, Lu)

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this