TY - JOUR
T1 - Upper limits for the rate coefficients for reactions of BrO with Formaldehyde and HBr
AU - Orlando, J. J.
AU - Ramacher, B.
AU - Tyndall, G. S.
PY - 2000/9/1
Y1 - 2000/9/1
N2 - The reactions of the BrO radical with hydrogen bromide, BrO + HBr → HOBr + Br (R4) and with HCHO, BrO + HCHO → HOBr + HCO (R5) have been studied at 298 K, 1 atm. pressure in an environmental chamber. No conclusive evidence for the occurrence of either reaction was found and upper limits for both reaction rate coefficients are reported (k4, k5 < 4 x 10-15 cm3 molecule-1 s-1). These upper limits are about 4-5 times lower than recent estimates [Hansen et al., 1999a,b].
AB - The reactions of the BrO radical with hydrogen bromide, BrO + HBr → HOBr + Br (R4) and with HCHO, BrO + HCHO → HOBr + HCO (R5) have been studied at 298 K, 1 atm. pressure in an environmental chamber. No conclusive evidence for the occurrence of either reaction was found and upper limits for both reaction rate coefficients are reported (k4, k5 < 4 x 10-15 cm3 molecule-1 s-1). These upper limits are about 4-5 times lower than recent estimates [Hansen et al., 1999a,b].
UR - https://www.scopus.com/pages/publications/0034352594
U2 - 10.1029/2000GL011725
DO - 10.1029/2000GL011725
M3 - Article
AN - SCOPUS:0034352594
SN - 0094-8276
VL - 27
SP - 2633
EP - 2636
JO - Geophysical Research Letters
JF - Geophysical Research Letters
IS - 17
ER -