UV absorption spectrum of BrOCl

James B. Burkholder; Gary Knight; John J. Orlando

doi:10.1016/S1010-6030(00)00261-6

UV absorption spectrum of BrOCl

James B. Burkholder, Gary Knight, John J. Orlando

Experimental Science Section

National Oceanic and Atmospheric Administration

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The UV absorption cross sections for BrOCl in the gas phase have been measured over the wavelength range 230-390nm. Absorption measurements were made at 298K using a 100cm long absorption cell and a diode array spectrometer. BrOCl was generated in the gas phase by exposing a BrCl/Cl₂/Br₂ gas mixture to solid HgO. The BrOCl absorption spectrum showed peaks at 272 (2.00×10^-18cm² per molecule) and 320nm (0.574×10^-18cm² per molecule). Absorption cross sections were determined by mass balance following the decomposition of the gas mixture.

Original language	English
Pages (from-to)	133-137
Number of pages	5
Journal	Journal of Photochemistry and Photobiology A: Chemistry
Volume	134
Issue number	1-2
DOIs	https://doi.org/10.1016/S1010-6030(00)00261-6
State	Published - Jun 2 2000

Keywords

BrOCl
Cross section
UV absorption spectrum

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10.1016/S1010-6030(00)00261-6

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title = "UV absorption spectrum of BrOCl",

abstract = "The UV absorption cross sections for BrOCl in the gas phase have been measured over the wavelength range 230-390nm. Absorption measurements were made at 298K using a 100cm long absorption cell and a diode array spectrometer. BrOCl was generated in the gas phase by exposing a BrCl/Cl2/Br2 gas mixture to solid HgO. The BrOCl absorption spectrum showed peaks at 272 (2.00×10-18cm2 per molecule) and 320nm (0.574×10-18cm2 per molecule). Absorption cross sections were determined by mass balance following the decomposition of the gas mixture.",

keywords = "BrOCl, Cross section, UV absorption spectrum",

author = "Burkholder, \{James B.\} and Gary Knight and Orlando, \{John J.\}",

year = "2000",

month = jun,

day = "2",

doi = "10.1016/S1010-6030(00)00261-6",

language = "English",

volume = "134",

pages = "133--137",

journal = "Journal of Photochemistry and Photobiology A: Chemistry",

issn = "1010-6030",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - UV absorption spectrum of BrOCl

AU - Burkholder, James B.

AU - Knight, Gary

AU - Orlando, John J.

PY - 2000/6/2

Y1 - 2000/6/2

N2 - The UV absorption cross sections for BrOCl in the gas phase have been measured over the wavelength range 230-390nm. Absorption measurements were made at 298K using a 100cm long absorption cell and a diode array spectrometer. BrOCl was generated in the gas phase by exposing a BrCl/Cl2/Br2 gas mixture to solid HgO. The BrOCl absorption spectrum showed peaks at 272 (2.00×10-18cm2 per molecule) and 320nm (0.574×10-18cm2 per molecule). Absorption cross sections were determined by mass balance following the decomposition of the gas mixture.

AB - The UV absorption cross sections for BrOCl in the gas phase have been measured over the wavelength range 230-390nm. Absorption measurements were made at 298K using a 100cm long absorption cell and a diode array spectrometer. BrOCl was generated in the gas phase by exposing a BrCl/Cl2/Br2 gas mixture to solid HgO. The BrOCl absorption spectrum showed peaks at 272 (2.00×10-18cm2 per molecule) and 320nm (0.574×10-18cm2 per molecule). Absorption cross sections were determined by mass balance following the decomposition of the gas mixture.

KW - BrOCl

KW - Cross section

KW - UV absorption spectrum

UR - https://www.scopus.com/pages/publications/0008494775

U2 - 10.1016/S1010-6030(00)00261-6

DO - 10.1016/S1010-6030(00)00261-6

M3 - Article

AN - SCOPUS:0008494775

SN - 1010-6030

VL - 134

SP - 133

EP - 137

JO - Journal of Photochemistry and Photobiology A: Chemistry

JF - Journal of Photochemistry and Photobiology A: Chemistry

IS - 1-2

ER -

UV absorption spectrum of BrOCl

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Keywords

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